Technical Info Sheet #31
Degassing is an umbrella term for a phenomenon that is easily observable as deviation from a powder coating surface. During the process, small craters, holes and sometimes blisters form on the powder coating. This is called degassing and the holes “pinholes.”
These defects are undesirable not only for aesthetic reasons, but also because of their reduced corrosion properties. Moisture and contamination can enter these openings leading to oxide formation of the underlying zinc layer.
The phenomenon of degassing can occur from usually rough or porous substrates such as steel, but frequently occurs when coating galvanized steel. Either the workpiece is galvanized after construction, or the workpiece is fabricated from hot-dip galvanized sheet material, or the workpiece is coated with a metallization layer after construction, known as thermal spraying.
The main cause of degassing is usually moisture or the reaction due to contaminants that want to escape from and from the galvanized steel in the powder coating furnace. Sometimes the cause is the powder itself. The powder then does not possess the property that the flow process takes place for a sufficiently long time. In short, the path between liquefaction of the powder and curing of the powder is not “long” enough to have degassing take place completely.
WHAT CAUSES DEGASSING?
Contamination of the surface to be coated.
Pinholes and blisters are often caused by a contaminated surface (contamination). This is the case when you do not thoroughly clean a surface before powder coating. Oil, grease and other forms of contamination left on the surface turn into vapor under the elevated temperature and have nowhere to go when trapped by the powder coating, so they just burst through, creating pinholes. If the paint shop uses compressed air for cleaning and blowing off, it should also be clean, oil-free and dry. Actually, these causes belong to improper work. Therefore, degassing due to contamination is rather a rare phenomenon.
Powder coating thickness
Coatings should be applied in relatively thin layers. If you apply a thick coat, gases may be released during the curing process that want to make their way onto the surface of the coating. When the powder cures during that process, these gas bubbles may then cause craters or blisters. It is essential to ensure that the coating thickness does not contribute to the problem.
Substrate
If the substrate is somewhat porous, for example, after the application of a galvanized coating, gases may escape from the pores. This degassing occurs when the object is heated in the furnace. The gas formed then escapes through the applied powder coating, which will cure after a flow phase. If the curing takes place and not all the gas has escaped, small craters or bubbles remain visible after coating.
Castings
Castings are rarely powder-coated when galvanized. The problem with cast metal is that it can give off a lot of gases during the powder coating process. This is because the casting process itself often traps gases in the metal because of minute voids and openings. Hot-dip galvanizing of castings can also cause problems and produce variable results.
HOW ARE THESE ANOMALIES TO BE RESOLVED?
Overcoating
By first slightly sanding the object until the surface is sufficiently flat and then applying an additional coating layer, the surface can be greatly visually improved. In addition, the thickness of the powder coating will increase, thereby improving corrosion resistance through improved barrier action.
Re-coating
Removing the object from the powder coating and starting over. The powder coating is removed thermally or chemically. During the thermal stripping process, the structure of the zinc-iron alloy layers may change in such a way that there may be reduced adhesion. Then the object will have to be re-galvanized (= re-galvanizing). After cleaning, keep a close eye on tight compliance with all process parameters to ensure optimal results.
HOW IS DEGASSING PREVENTED?
Degassing cannot always be prevented, as you will understand from this document. Some degassing is therefore permitted and cannot lead to rejection. The standard and the code of practice both indicate that a certain assessment distance should be respected. Usually these craters are not visible at the mentioned distances. Outgassing can largely be prevented by properly preparing your materials, applying the proper handling for the powder coating process and handling your materials properly. These are the steps:
Clean all contamination
Clean and degrease the object you are going to powder coat thoroughly and carefully. Be sure to wear gloves so that your hands do not leave oil and grease on the surface of the object.
Beware when storing galvanized steel
Freshly galvanized steel will directly form zinc oxides in the atmosphere and react with elements in the outside air to form a zinc patina layer. If the materials are improperly stored, long-term moisture exposure can result in what is known as white rust. White rust is a surface contaminant and must be removed. Oxides must also be removed.
Controlling powder coating thickness
Some jobs require a thicker powder coating than others, but the desired coating thickness need not be applied in a single layer. By understanding the materials used in a coating and applying multiple layers, degassing caused by a powder coating that is too thick on the object can be prevented.
Use a primer
Applying a suitable primer layer helps ensure that any gases released during the heating process are processed through the primer.
They can then not bubble up into the color layer of the powder coating itself. Obviously, this is no substitute for thorough cleaning and proper pre-treatment.
Adding additives
The gases that escape in the oven penetrate the still liquid coating layer as the coating gradually cures. Eventually, this causes blistering when the coating is fairly hard and no longer allows the gases to pass through. Certain additives can be used that cause the powder to remain in liquid form longer. This gives the gases more time to escape before the powder hardens. Specialized suppliers typically carry “degassing-friendly” powders.
Degassing the object beforehand
Since degassing is caused by gases released by expansion when the object is heated in the oven, this can be prevented by preheating the object before powder coating. During this “pre-baking,” gas bubbles can escape from the material without powder coating. Usually maintain a temperature 20-30 ºC higher than the required curing temperature (see the powder supplier’s specification for this) and then for double the object’s residence time in the oven. Then do not allow the object to cool completely (approximately to 40-50 ºC ) before starting to apply the powder to avoid condensation of moisture on the surface.
Pretreatment adjustment
Besides the escape of gases due to contaminants, vapor or gas also escapes from the pores of the material to be coated.
So also moisture from the chemical pretreatment of a powder coating plant. For this reason, for degassing-sensitive surfaces, it is sometimes better to opt for abrasive blasting as pretreatment.
Furthermore, it is important to assess the galvanized coating. A rough, dull and gray zinc coating is more susceptible to degassing than a shiny, silvery smooth zinc coating. Sometimes it may be that a gray, dull zinc coating can be seen that is reasonably smooth. If so, the zinc layer may have been post-treated by annealing. That is heating the object again so that the zinc layer acquires other properties. You understand that after this second heating, the chance of degassing is greatly reduced.
Furthermore, the design of the object can play a role. In the oven of powder coating plant, a good heat transfer must be able to take place. The object should reach temperature reasonably quickly and evenly, so to speak. Hollow profiles or locally large amounts of steel mass can lead to deviations that cause degassing to start only once the coating is already curing.
EN ISO 12944-1:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 1: General introduction (ISO 12944-1:2017)
EN ISO 12944-2:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 2: Classification of environments (ISO 12944-2:2017)
EN ISO 12944-3:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 3: Design considerations (ISO 12944-3: 2017)
EN ISO 12944-4:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 4: Types of surface and surface preparation (ISO 12944-4:2017)
EN ISO 12944-5:2019
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 5: Protective paint systems (ISO 12944-5:2019)
EN ISO 12944-6:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 6: Test methods for laboratory performance (ISO 12944-6:2018)
EN ISO 12944-7:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 7: Performance and supervision of painting operations (ISO 12944-7:2017)
EN ISO 12944-8:2018
Paints and varnishes – Corrosion protection of steel structures by protective paint systems – Part 8: Development of specifications for new work and maintenance (ISO 12944-8:2017)
EN 15773
Industrial application of organic powder coatings on hot-dip galvanized or sherardized steel (duplex systems) – Specifications, recommendations and guidelines